Copper-nickel alloys, properties, and applications

 

The basic copper-nickel alloying system is relatively simple, improving the overall characteristics of copper in terms of strength and corrosion resistance while maintaining high inherent resistance to biofouling. The addition of nickel to copper increases strength and many corrosion resistance characteristics.

Alloys with a nickel content greater than 10% and those which are more highly alloyed with chromium, aluminum, and tin are used where greater resistance to flow conditions, sand abrasion, wear, and seizure, as well as higher mechanical properties, are required.

v  Features of Copper-Nickel Alloys-

·         Corrosion Resistance- 90-10 and 70-30 Copper Nickel Alloy Flanges were originally developed for naval condensers and piping. Their corrosion resistance is obtained by forming a complex surface film which develops by interaction with the seawater itself, thus protecting the underlying metal.

·         Biofouling – the adhesion of slime algae, sea mosses, sea anemones, barnacles, and mollusks (oysters and mussels) on surfaces of marine structures – can have a strong negative effect on system performance.

·         Mechanical Properties- The addition of nickel to copper improves the alloy's strength and durability. The mechanical properties of copper-nickel alloys combine good tensile strength and excellent ductility during annealing. As solid solution alloys, alloys 9010 and 7030 cannot be age-hardened. Higher tensile strength and hardness can only be achieved when the alloys are cold worked.

·         Cryogenic Properties- Cu-Ni alloys were the first metals used in the fabrication of low-temperature equipment for the liquefaction and storage of cryogenic fluids. Copper and many copper alloys retain ductility at low temperatures. Their unusual properties of retaining ductility at low temperatures and exhibiting good thermal conductivity are advantageous for heat exchangers and other components in cryogenic plants and low-temperature processing and storage equipment.



·        Environmental Properties

  §  90-10 Cu-Ni is a single-phase alloy with a melting point above 1100C.

  §  In the case of a hydrocarbon fire, copper-nickel does not generate toxic fumes. It will not show degradation in an uncontrolled manner.

  §  Cu-Ni has inherent high resistance to biofouling. Chlorination can be reduced or, in some instances, avoided.

  §  Cu-Ni can be recycled. It can be 100% remelted and reused.


v  Application of Cu-Ni Alloy

 

·         Applications for copper-nickel alloys can include condensers, coolers and other heat exchangers, onboard seawater desalination plants, systems for compressed air, sanitary systems, bilge, ballast water, brine, fire mains and sprinklers, fuel oil, lube oil, warm water heating, grey and black water, hydraulic lines and tank heating.

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